Full Text Journal Articles by
Author Tyler Carter

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Thiocyanate complexes of the lanthanides, Am and Cm.

Richard E Wilson, Tyler J Carter, Matthieu Autillo, Samantha Stegman,

The synthesis and single crystal structures of Am(iii) and Cm(iii) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal-thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal-ligand interactions. ... Read more >>

Chem Commun (Camb) (Chemical communications (Cambridge, England))
[2020, 56(17):2622-2625]

Cited: 3 times

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Synthesis, structure, ultrafast kinetics, and light-induced dynamics of CuHETPHEN chromophores.

Lars Kohler, Dugan Hayes, Jiyun Hong, Tyler J Carter, Megan L Shelby, Kelly A Fransted, Lin X Chen, Karen L Mulfort,

Five heteroleptic Cu(i)bis(phenanthroline) chromophores with distinct variation in the steric bulk at the 2,9-phenanthroline position were synthesized using the HETPHEN method, and their ground and excited state properties are described. Analysis of the crystal structures reveals a significant distortion from tetrahedral geometry around the Cu(i) centre which is attributed to ... Read more >>

Dalton Trans (Dalton transactions (Cambridge, England : 2003))
[2016, 45(24):9871-9883]

Cited: 5 times

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Discovery of low energy pathways to metal-mediated B 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 N bond reduction guided by computation and experiment.

Tyler J Carter, Zachariah M Heiden, Nathaniel K Szymczak,

This manuscript describes a combination of DFT calculations and experiments to assess the reduction of borazines (B-N heterocycles) by η<sup>6</sup>-coordination to Cr(CO)<sub>3</sub> or [Mn(CO)<sub>3</sub>]<sup>+</sup> fragments. The energy requirements for borazine reduction are established as well as the extent to which coordination of borazine to a transition metal influences hydride affinity, ... Read more >>

Chem Sci (Chemical science)
[2015, 6(12):7258-7266]

Cited: 3 times

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Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes.

Tyler J Carter, Richard E Wilson,

The synthesis, X-ray crystal structure, vibrational and optical spectroscopy for the eight-coordinate thiocyanate compounds, [Et4 N]4 [Pu(IV) (NCS)8 ], [Et4 N]4 [Th(IV) (NCS)8 ], and [Et4 N]4 [Ce(III) (NCS)7 (H2 O)] are reported. Thiocyanate was found to rapidly reduce plutonium to Pu(III) in acidic solutions (pH<1) in the presence of ... Read more >>

Chemistry (Chemistry (Weinheim an der Bergstrasse, Germany))
[2015, 21(44):15575-15582]

Cited: 1 time

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Boron clusters as highly stable magnesium-battery electrolytes.

Tyler J Carter, Rana Mohtadi, Timothy S Arthur, Fuminori Mizuno, Ruigang Zhang, Soichi Shirai, Jeff W Kampf,

Boron clusters are proposed as a new concept for the design of magnesium-battery electrolytes that are magnesium-battery-compatible, highly stable, and noncorrosive. A novel carborane-based electrolyte incorporating an unprecedented magnesium-centered complex anion is reported and shown to perform well as a magnesium-battery electrolyte. This finding opens a new approach towards the ... Read more >>

Angew Chem Int Ed Engl (Angewandte Chemie (International ed. in English))
[2014, 53(12):3173-3177]

Cited: 26 times

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Free light chain content in culture media reflects recombinant monoclonal antibody productivity and quality.

Prachi Bhoskar, Brett Belongia, Robert Smith, Seongkyu Yoon, Tyler Carter, Jin Xu,

Monoclonal antibodies (mAbs) are currently the dominant class of biopharmaceuticals. Due to the high dosage requirements of most mAb therapeutics, high productivity and low aggregation are prevailing criteria during cell line generation and process development. Given that light chains (LCs) play an important role in antibody folding and assembly, and ... Read more >>

Biotechnol Prog (Biotechnology progress)
[2013, 29(5):1131-1139]

Cited: 12 times

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Reduction of borazines mediated by low-valent chromium species.

Tyler J Carter, Jeff W Kampf, Nathaniel K Szymczak,

Recharging spent BN fuel: {Cr(CO)(3)} mediates the reduction of borazines by hydride and methyl nucleophiles to generate anionic complexes of dearomatized hexamethylborazine. Subsequent quenching leads to the release of a substituted cyclotriborazane, successfully demonstrating the stepwise reduction of a B=N bond. ... Read more >>

Angew Chem Int Ed Engl (Angewandte Chemie (International ed. in English))
[2012, 51(52):13168-13172]

Cited: 4 times

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