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Enhancing room-temperature NO2 detection of cobalt phthalocyanine based gas sensor at an ultralow laser exposure.

Wenkai Jiang, Tao Wang, Xinwei Chen, Bolong Li, Min Zeng, Nantao Hu, Yanjie Su, Zhihua Zhou, Yafei Zhang, Zhi Yang,

Metal phthalocyanines (MPcs) have attracted great interest in the gas sensing field, but the long recovery time with hard desorption of gas has hindered their further practical application. The combination of cobalt and carboxyl groups increases the electron concentration. Herein, cobalt phthalocyanine (CoPc-COOH) modified with carboxyl groups was prepared and ... Read more >>

Phys Chem Chem Phys (Physical chemistry chemical physics : PCCP)
[2020, 22(33):18499-18506]

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Synthesis of 7-hydroxy-6H-naphtho[2,3-c]coumarin via a TsOH-mediated tandem reaction.

Ding Wang, Zhishuang Ma, Nana Wang, Chenyu Li, Tao Wang, Yong Liang, Zunting Zhang,

A concise and efficient method for the synthesis of 7-hydroxy-6H-naphtho[2,3-c]coumarin using available 1-(2-hydroxyphenyl)-2-phenylethanone and Meldrum's acid has been developed. This transformation involved a tandem aldol reaction/lactonization/Friedel-Crafts reaction to form a lactone ring and a benzene ring. It showed high atom economy with water and acetone as the byproducts. Mechanism studies ... Read more >>

Chem. Commun. (Camb.) (Chemical communications (Cambridge, England))
[2020, 56(71):10369-10372]

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A target-mediated fuel-initiated molecular machine for high-sensitive fluorescence assay of the ZIKV gene via strand displacement reaction-based signal recovery and cycling amplification.

Chunyuan Song, Yuzhou Sun, Jingjing Zhang, Tao Wang, Yingxin Wang, Ying Liu, Lianhui Wang,

Zika virus (ZIKV) is a serious threat to human health due to its widespread human arboviral infections, and early diagnosis is one of the keys to preventing infections from spreading, but there is a lack of highly sensitive and specific detection. In this work, a target-mediated fuel-initiated molecular machine was ... Read more >>

Analyst (The Analyst)
[2020, 145(16):5475-5481]

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Trace metals dramatically boost oxygen electrocatalysis of N-doped coal-derived carbon for zinc-air batteries.

Huimin Liu, Xinning Huang, Zhenjie Lu, Tao Wang, Yaming Zhu, Junxia Cheng, Yue Wang, Dongling Wu, Zhenyu Sun, Alex W Robertson, Xingxing Chen,

The commercialization of metal-air batteries requires efficient, low-cost, and stable bifunctional electrocatalysts for reversible electrocatalysis of the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). The modification of natural coal by heteroatoms such as N and S, or metal oxide species, has been demonstrated to form very promising ... Read more >>

Nanoscale (Nanoscale)
[2020, 12(17):9628-9639]

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Selective detection of sulfide in human lung cancer cells with a blue-fluorescent "ON-OFF-ON" benzimidazole-based chemosensor ensemble.

Chak-Shing Kwan, Tao Wang, Sing-Ming Chan, Zongwei Cai, Ken Cham-Fai Leung,

A completely water-soluble, high quantum yield blue-fluorescent benzimidazole derivative (AQ), containing a rigid benzimidazole-thiophene structure, was synthesized. Among 21 metal ions, the fluorescence of AQ was selectively turned off by Cu2+ to form an AQ-Cu2+ ensemble. Thereafter, the fluorescence of the AQ-Cu2+ ensemble was turned on by sulfide (S2-) with ... Read more >>

Dalton Trans (Dalton transactions (Cambridge, England : 2003))
[2020, 49(17):5445-5453]

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Covalent sulfur embedding in inherent N,P co-doped biological carbon for ultrastable and high rate lithium-sulfur batteries.

Jiarui Li, Jian Zhou, Tao Wang, Xu Chen, Yaxuan Zhang, Qiang Wan, Jian Zhu,

Lithium-sulfur (Li-S) batteries are attracting extensive interest owing to their low cost and potential for applications in high-density energy storage systems. However, their widespread application is severely plagued by poor cycling stability, inferior rate capability and low coulombic efficiency, which are largely attributed to the shuttling effect of soluble polysulfides. ... Read more >>

Nanoscale (Nanoscale)
[2020, 12(16):8991-8996]

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A two-step gas/liquid strategy for the production of N-doped defect-rich transition metal dichalcogenide nanosheets and their antibacterial applications.

Tao Wang, Xiao Zhang, Linqiang Mei, Dongqing Ma, You Liao, Yan Zu, Peng Xu, Wenyan Yin, Zhanjun Gu,

Herein, we developed a general two-step gas expansion and exfoliation strategy based on a urea-assisted hydrothermal process combined with sonication exfoliation for the production of nitrogen (N)-doped plus defect-rich transition metal dichalcogenide (TMD) nanosheets (NSs) such as N-MoS2 and N-WS2 NSs. The interlayers of bulk MoS2 (or WS2) were expanded ... Read more >>

Nanoscale (Nanoscale)
[2020, 12(15):8415-8424]

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Construction of a combined enzyme system of graphene oxide and manganese peroxidase for efficient oxidation of aromatic compounds.

Shichao Yang, Jun Yang, Tao Wang, Liuqing Li, Siming Yu, Rong Jia, Ping Chen,

Manganese peroxidase (MnP) from Irpex lacteus F17 has potential use as a biocatalyst in the field of environmental biotechnology because of its unique properties and ability to decompose harmful aromatic compounds. However, its requirement of harsh acidic reaction conditions and its insufficient catalytic activity restrict its practical applications. Here, we ... Read more >>

Nanoscale (Nanoscale)
[2020, 12(14):7976-7985]

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Synthesis of planar chiral ferrocenes via a Pd(0)-catalyzed syn-carbopalladation/asymmetric C-H alkenylation process.

Lixiang Jia, Xiaobing Liu, An-An Zhang, Tao Wang, Yuanzhao Hua, Heng Li, Lantao Liu,

The Pd(0)-catalyzed tandem intermolecular syn-carbopalladation/asymmetric C-H alkenylation reaction of N-ferrocenyl propiolamides with aryl iodides has been realized, generating planar chiral ferrocene[1,2-d] pyrrolinones in good yields. Through employing BINOL-derived phosphoramidite ligands, up to 95% ee is achieved. ... Read more >>

Chem. Commun. (Camb.) (Chemical communications (Cambridge, England))
[2020, 56(11):1737-1740]

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A multiple mode integrated biosensor based on higher order Fano metamaterials.

Xin Yan, Zhang Zhang, Lanju Liang, Maosheng Yang, Dequan Wei, Xiaoxian Song, Haiting Zhang, Yuying Lu, Longhai Liu, Mengjin Zhang, Tao Wang, Jianquan Yao,

A multiple mode integrated biosensor based on higher order Fano metamaterials (FRMMs) is proposed. The frequency shifts (Δf) of x-polarized quadrupolar (Qx), octupolar (Ox), hexadecapolar (Hx), y-polarized quadrupolar (Qy) and octupolar (Oy) Fano resonance modes are integrated to detect the concentration of lung cancer cells. In experiments, the concentrations of ... Read more >>

Nanoscale (Nanoscale)
[2020, 12(3):1719-1727]

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Green synthesis of mesoporous MnNbOx oxide by a liquid induced self-assembly strategy for low-temperature removal of NOx.

Huifang Cheng, Guodong Feng, Zhenzhen Yang, Tao Wang, Francis Okejiri, Junbin Tan, Minjie Zhao, Jixing Liu, Jian Liu, Zhen Zhao,

Herein, we present a facile, sustainable, and highly efficient ionic liquid induced self-assembly protocol to construct a highly porous MnNbOx oxide with exceptionally high catalytic activity for NOx removal at low temperatures and excellent tolerance to H2O and SO2 poisoning. ... Read more >>

Chem. Commun. (Camb.) (Chemical communications (Cambridge, England))
[2019, 55(100):15073-15076]

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Nucleus segmentation of cervical cytology images based on multi-scale fuzzy clustering algorithm.

Jinjie Huang, Tao Wang, Dequan Zheng, Yongjun He,

In the screening of cervical cancer cells, accurate identification and segmentation of nucleus in cell images is a key part in the early diagnosis of cervical cancer. Overlapping, uneven staining, poor contrast, and other reasons present challenges to cervical nucleus segmentation. We propose a segmentation method for cervical nuclei based ... Read more >>

Bioengineered (Bioengineered)
[2020, 11(1):484-501]

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3D spheroids generated on carbon nanotube-functionalized fibrous scaffolds for drug metabolism and toxicity screening.

Jiaojun Wei, Jinfu Lu, Maohua Chen, Songzhi Xie, Tao Wang, Xiaohong Li,

The mechanical and electrical stimuli have a profound effect on the cellular behavior and function. In this study, a series of conductive nanofibrous scaffolds are developed by blend electrospinning of poly(styrene-co-maleic acid) (PSMA) and multiwalled-carbon nanotubes (CNTs), followed by grafting galactose as cell adhesion cues. When the mass ratios of ... Read more >>

Biomater Sci (Biomaterials science)
[2019, 8(1):426-437]

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Exogenous-oxidant- and catalyst-free electrochemical deoxygenative C2 sulfonylation of quinoline N-oxides.

Minbao Jiang, Yong Yuan, Tao Wang, Yunkui Xiong, Jun Li, Huijiao Guo, Aiwen Lei,

An exogenous-oxidant- and catalyst-free electrochemical deoxygenative C2 sulfonylation reaction has been achieved. By employing quinoline N-oxides as the starting materials, the electrochemical C-H sulfonylation of electron-deficient quinolines was indirectly achieved at room temperature and a variety of sulfonylated quinoline derivatives were synthesized in modest to high yield with excellent regioselectivity. ... Read more >>

Chem. Commun. (Camb.) (Chemical communications (Cambridge, England))
[2019, 55(92):13852-13855]

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Peritoneal dialysis outcomes in patients with nephrotic syndrome: a propensity score-matched cohort study.

Si-Jia Zhou, Ya-Kun Cong, Qing-Feng Han, Wen Tang, Tao Wang,

INTRODUCTION:It is unclear whether patients with end-stage renal disease (ESRD) and nephrotic syndrome (NS) can be treated with peritoneal dialysis (PD). OBJECTIVES:To investigate the outcomes of PD treatment in ESRD patients with or without NS. METHODS:In this retrospective cohort study, all incident patients with ESRD and NS who started PD ... Read more >>

Ren Fail (Renal failure)
[2020, 42(1):684-692]

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Serum Sphingosine-1-phosphate level and peritonitis in peritoneal dialysis patients.

Qiong Bai, Hong-Xia Guo, Chun-Yan Su, Qing-Feng Han, Tao Wang, Wen Tang,

BACKGROUND:Given the important role of Sphingosine-1-phosphate (S1P) in maintaining the hemostasis in intestinal barrier function and regulation of inflammation and immune, we hypothesize that S1P might be a biomarker to predict peritonitis in peritoneal dialysis (PD) patients. METHODS:In this case-control study, 78 stable, continuous ambulatory peritoneal dialysis patients were enrolled ... Read more >>

Ren Fail (Renal failure)
[2020, 42(1):829-835]

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Fluorescent fibrous mats assembled with self-propagating probes for visual sensing of hydrogen peroxide and choline.

Long Zhao, Zhanlin Zhang, Maohua Chen, Yuan Liu, Tao Wang, Xiaohong Li,

Challenges remain in the facile, rapid and sensitive detection of substances at ultralow levels. In the current study, visual sensors of hydrogen peroxide (H2O2) and choline are developed via the integration of an ultrafine fibrous substrate and self-propagating and aggregation-induced emission (AIE) probes. Self-immolative probes (SIPs) composed of phenylboronic acid ... Read more >>

Analyst (The Analyst)
[2019, 144(18):5624-5636]

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Treatment of COVID-19 Patients with Prolonged Post-Symptomatic Viral Shedding with Leflunomide -- a Single-Center, Randomized, Controlled Clinical Trial.

Mengmei Wang, Yang Zhao, Weihua Hu, Dong Zhao, Yunting Zhang, Tao Wang, Zhishui Zheng, Xiaochen Li, Shaolin Zeng, Zhenlian Liu, Li Lu, Zhihui Wan, Ke Hu,

OBJECTIVE:To evaluate the efficacy and safety of leflunomide, an approved dihydroorotate dehydrogenase inhibitor, to treat COVID-19 patients with prolonged post-symptomatic viral shedding. METHODS:We conducted a prospective, randomized, controlled, open-label trial involving hospitalized adult COVID-19 patients with prolonged PCR positivity. Patients were randomly assigned to receive either leflunomide (50 mg, q12h, three ... Read more >>

Clin. Infect. Dis. (Clinical infectious diseases : an official publication of the Infectious Diseases Society of America)
[2020, :]

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Ultrafast and Programmable Shape Memory Hydrogel of Gelatin Soaked in Tannic Acid Solution.

Shurui Yang, Yuancheng Zhang, Tao Wang, Weixiang Sun, Zhen Tong,

Shape memory hydrogels have been paid plenty of attention as a kind of intelligent soft material. However, complicated preparation, slow and uncontrollable shape change have hindered their applications in smart actuators. In this work, a temperature responsive strong hydrogel was prepared by a facial soaking method without any chemical reactions, ... Read more >>

ACS Appl Mater Interfaces (ACS applied materials & interfaces)
[2020, :]

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Involvement of kindlin-2 in irisin's protection against ischaemia reperfusion-induced liver injury in high-fat diet-fed mice.

Jia Zhang, Yifan Ren, Jianbin Bi, Mengzhou Wang, Lin Zhang, Tao Wang, Shasha Wei, Xingyi Mou, Yi Lv, Rongqian Wu,

Liver steatosis is associated with increased ischaemia reperfusion (I/R) injury. Our previous studies have shown that irisin, an exercise-induced hormone, mitigates I/R injury via binding to αVβ5 integrin. However, the effect of irisin on I/R injury in steatotic liver remains unknown. Kindlin-2 directly interacts with β integrin. We therefore suggest ... Read more >>

J. Cell. Mol. Med. (Journal of cellular and molecular medicine)
[2020, :]

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A self-sorted gel network formed by heating a mixture of soy and cod proteins.

Chao Wu, Xinyu Yan, Tao Wang, Wuchao Ma, Xianbing Xu, Ming Du,

The development of binary protein networks featuring superior nutritional and rheological properties is an intriguing, as well as challenging, aspect in the food industry. In this study, a novel, self-assorted double protein network was constructed, which was achieved by simply heating soy protein (SP) and cod protein (CP) at 100 ... Read more >>

Food Funct (Food & function)
[2019, 10(8):5140-5151]

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Endobronchial ultrasound-guided versus computed tomography-guided biopsy for peripheral pulmonary lesions: a meta-analysis.

Yu-Fei Fu, Jing-Hao Zhang, Tao Wang, Yi-Bing Shi,

BACKGROUND:Both endobronchial ultrasound-guided transbronchial biopsy (EBUS-TBB) and computed tomography-guided transthoracic needle biopsy (CT-TTNB) are approaches commonly utilized to diagnose peripheral pulmonary lesions (PPLs). The present meta-analysis was therefore designed to provide more reliable evidence regarding the relative advantages of these two approaches to PPL diagnosis in order to guide clinical ... Read more >>

Clin Respir J (The clinical respiratory journal)
[2020, :]

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Chemokine Receptor 7 (CCR7) Participates in the Migration of DCs and Has Impact on the Progression of Primary Pterygium

Ting Wang, Tao Wang, Huanqi Ni, Lei Zhong, Huanhuan Cheng, Tiancheng Bao, Xiuhua Jia, Jun Xia, Xinyu Liu, Haotian Lin, Shiqi Ling,

Abstract Background : The effect of chemokine receptors and their ligands for dendritic cells (DCs) plays a critical role in the immune response, but whether chemokine receptor 7 (CCR7) has an impact on DCs migrating in pterygia remains unclear. The aim of this article is to investigate the involvement of ... Read more >>

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Asparagine endopeptidase inhibitor protects against fenpropathrin-induced neurodegeneration via suppressing α-synuclein aggregation and neuroinflammation.

Ting Yu, Fang Wan, Chaoyang Liu, Xingyu Zhang, Zehua Liu, Jichun Zhang, Jing Xiong, Tao Wang, Zhentao Zhang,

Exposure to fenpropathrin (Fen), one of the most widely used pyrethroid pesticides, has been reported to increase the incidence of Parkinson's disease (PD). However, the molecular mechanisms underlying Fen-induced Parkinsonism remain unknown. Here we investigated the role of the lysosomal protease asparagine endopeptidase (AEP) in Fen-induced neurodegeneration and tested the ... Read more >>

Eur. J. Pharmacol. (European journal of pharmacology)
[2020, :173586]

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Compromised immune status of patients with post-liver transplant biliary complications.

Hong Lei, Min Tian, Xiao-Gang Zhang, Lie-Su Meng, Wen-Hua Zhu, Xue-Min Liu, Meng-Zhou Wang, Tao Wang, Peng-Kang Chang, Huan Chen, Bo Wang, Rong-Qian Wu, Yi Lyu,

Chin. Med. J. (Chinese medical journal)
[2020, :]

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