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Author Robert K Ghazaryan


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Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids.

Tigran S Kurtikyan, Vardan A Hayrapetyan, Garik G Martirosyan, Robert K Ghazaryan, Alexei V Iretskii, Hailiang Zhao, Kristine Pierloot, Peter C Ford,

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state. ... Read more >>

Chem Commun (Camb) (Chemical communications (Cambridge, England))
[2012, 48(99):12088-12090]

Cited: 3 times

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