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HERFD-XANES probes of electronic structures of ironII/III carbene complexes.

Meiyuan Guo, Om Prakash, Hao Fan, Lisa H M de Groot, Valtýr Freyr Hlynsson, Simon Kaufhold, Olga Gordivska, Nicolás Velásquez, Pavel Chabera, Pieter Glatzel, Kenneth Wärnmark, Petter Persson, Jens Uhlig,

Iron centered N-heterocyclic carbene (Fe-NHC) complexes have shown long-lived excited states with charge transfer character useful for light harvesting applications. Understanding the nature of the metal-ligand bond is of fundamental importance to rationally tailor the properties of transition metal complexes. The high-energy-resolution fluorescence detected X-ray absorption near edge structure (HERFD-XANES) ... Read more >>

Phys Chem Chem Phys (Physical chemistry chemical physics : PCCP)
[2020, 22(16):9067-9073]

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From a layered iridium(iii)-cobalt(ii) organophosphonate to an efficient oxygen-evolution-reaction electrocatalyst.

Chwen-Haw Liao, Kun Fan, Song-Song Bao, Hao Fan, Xi-Zhang Wang, Zheng Hu, Mohamedally Kurmoo, Li-Min Zheng,

Bimetallic MOF precursors can produce a homogeneous distribution of mixed-metal oxides after calcination, and thus may provide high efficiency as electrocatalysts in the water splitting process. We designed a layered bimetallic-organophosphonate containing Ir, Co and P because the metal-oxides are well-known for their efficiency in the oxygen-evolution reaction (OER), especially ... Read more >>

Chem. Commun. (Camb.) (Chemical communications (Cambridge, England))
[2019, 55(92):13920-13923]

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Enhanced thermal stability of lactic acid bacteria during spray drying by intracellular accumulation of calcium

Yan Wang, Fan Hao, Wenjie Lu, Xiangshu Suo, Elise Bellenger, Nan Fu, Romain Jeantet, Xiao Dong Chen,

Lactococcus lactis ssp. cremoris and Lactobacillus acidophilus NCFM were cultured in growth media supplemented with CaCl2 to induce intracellular accumulation of Ca2+. Both strains grown with 10 mM Ca2+ demonstrated enhanced thermal stability, with increased survival after spray drying from 49.9% to 64.9% for the coccus and from 35.5% to ... Read more >>

(Journal of food engineering.)
[2020, 279:Not Available]

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Downregulation of HDAC8 expression decreases CD163 levels and promotes the apoptosis of macrophages by activating the ERK signaling pathway in recurrent spontaneous miscarriage.

Yongli Yao, Fan Hao, Lin-Chen Tang, Xiang-Hong Xu, Liping Jin,

Recurrent spontaneous miscarriage (RSM) is a systemic disorder that has been defined as two or more pregnancies lost before the 20th week of gestation. Although the impaired function of macrophages at the maternal-fetal interface has been reported to be associated with RSM, the underlying mechanisms have not been fully elucidated. ... Read more >>

Mol. Hum. Reprod. (Molecular human reproduction)
[2020, :]

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A homogeneous electrochemical DNA sensor on the basis of a self-assembled thiol layer on a gold support and by using tetraferrocene for signal amplification.

Tianjiao Ning, Fusheng Liao, Hanfeng Cui, Zhaojiang Yin, Guangqiang Ma, Lin Cheng, Nian Hong, Jun Xiong, Hao Fan,

An unmodified electrochemical biosensor has been constructed, which can directly detect DNA in homogeneous solution. The synthesized new compound tetraferrocene was used for signal amplification. The dual-hairpin probe DNA was tagged with a tetraferrocene at the 3' terminal and a thiol at the 5' terminal. Without being hybridized with target ... Read more >>

Mikrochim Acta (Mikrochimica acta)
[2020, 187(6):340]

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Development of a PHMB hydrogel-modified wound scaffold dressing with antibacterial activity.

Jian Jin, Zheng-Li Chen, Yang Xiang, Tao Tang, Hao Zhou, Xu-Dong Hong, Hao Fan, Xu-Dong Zhang, Peng-Fei Luo, Bing Ma, Guang-Yi Wang, Zhao-Fan Xia,

Current wound scaffold dressing constructs can facilitate wound healing but do not exhibit antibacterial activity, resulting in high infection rates. We aimed to endow wound scaffold dressing with anti-infective ability by polyhexamethylenebiguanide (PHMB). We prepared PHMB hydrogel at varying concentrations (0.25%, 0.5%, 1%, 2%) and assessed release and cytotoxicity. PHMB ... Read more >>

Wound Repair Regen (Wound repair and regeneration : official publication of the Wound Healing Society [and] the European Tissue Repair Society)
[2020, :]

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High-affinity agonist binding to C5aR results from a cooperative two-site binding mechanism

Andra Dumitru, Krishna Deepak, Heng Liu, Melanie Koehler, Cheng Zhang, Hao Fan, David Alsteens,

Abstract A current challenge in the field of life sciences is to decipher, in their native environment, the functional activation of cell surface receptors upon binding of complex ligands. Lack of suitable nanoscopic methods has hampered our ability to meet this challenge in an experimental manner. Here, we use for ... Read more >>

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Highly sensitive host-guest mode homogenous electrochemical thrombin signal amplification aptasensor based on tetraferrocene label.

Huihui Xu, Hanfeng Cui, Zhaojiang Yin, Guobing Wei, Fusheng Liao, Qingxia Shu, Guangqiang Ma, Lin Cheng, Nian Hong, Jun Xiong, Hao Fan,

The development of sensitive and convenient detection methods to monitor thrombin without the use of enzymes or complex nanomaterials is highly desirable for the diagnosis of cardiovascular diseases. In this article, tetraferrocene was first synthesized and then a sensitive and homogeneous electrochemical aptasensor was developed for thrombin detection based on ... Read more >>

Bioelectrochemistry (Bioelectrochemistry (Amsterdam, Netherlands))
[2020, 134:107522]

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Multi-signal amplification electrochemical DNA biosensor based on exonuclease III and tetraferrocene.

Zhaojiang Yin, Hanfeng Cui, Qingxia Shu, Chen Jin, Yan Lin, Jia Su, HuiLian Huang, Fusheng Liao, Guangqiang Ma, Nian Hong, Yunfeng Jiang, Hao Fan,

Homogeneous electrochemical DNA biosensors' unique qualities have been of great interest to researchers, mainly due to their high recognition efficiency in solutions. However, the processes of introducing additional markers and extra operations to obtain a signal are tedious and time consuming, which limits their overall potential applications. Herein, a novel ... Read more >>

J Mater Chem B (Journal of materials chemistry. B)
[2020, 8(18):4143-4150]

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The spatial differentiation of quality of rural life based on natural controlling factors: A case study of Gansu Province, China.

Fang Fang, Libang Ma, Hao Fan, Xinglong Che, Meimei Chen,

The laws of regional differentiation of county development and influencing factors on the quality of rural life (QRL), affect not only the vital interests of rural residents but also the scientific implementation of rural revitalization strategy. In this paper, taking 87 counties (cities, districts) of Gansu Province as the region ... Read more >>

J. Environ. Manage. (Journal of environmental management)
[2020, 264:110439]

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Directed Computational Evolution of Quorum-Quenching Lactonases from the Amidohydrolase Superfamily.

Maybelle Kho Go, Li Na Zhao, Bo Xue, Shreyas Supekar, Robert C Robinson, Hao Fan, Wen Shan Yew,

In this work, we present a generalizable directed computational evolution protocol to effectively reduce the sequence space to be explored in rational enzyme design. The protocol involves in silico mutation modeling and substrate docking to rapidly identify mutagenesis hotspots that may enhance an enzyme's substrate binding and overall catalysis. By ... Read more >>

Structure (Structure (London, England : 1993))
[2020, 28(6):635-642.e3]

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[Challenges and enlightenments of SPARC program on acupuncture and moxibustion researches in China].

Si-Ming Ma, Na-Na Yang, Hao Fan, Lu Wang, Jin Huang, Jing-Wen Yang, Cun-Zhi Liu,

The advantages of western medical research were analyzed and the differences between skin nerve stimulation in western medicine and acupuncture-moxibustion in TCM were compared, so as to inspire the scientific researches of acupuncture and moxibustion in China. The related literature was searched and the research basis, content and achievements of ... Read more >>

Zhongguo Zhen Jiu (Zhongguo zhen jiu = Chinese acupuncture & moxibustion)
[2020, 40(4):439-442]

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A sensitive homogenous aptasensor based on tetraferrocene labeling for thrombin detection.

Lin Cheng, Chen Xu, Hanfeng Cui, Fusheng Liao, Nian Hong, Guangqiang Ma, Jun Xiong, Hao Fan,

In this work, a novel homogeneous electrochemical aptasensor based on electrically assisted bond and tetraferrocene signal amplification was constructed for thrombin detection. Importantly, modification of the electrode is not necessary for this sensor, requiring only the construction of a simple and efficient probe. In addition, a brand new signal marker-tetraferrocene, ... Read more >>

Anal. Chim. Acta (Analytica chimica acta)
[2020, 1111:1-7]

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Precise lysosome pH indicator based on self-decomposable nanoparticles

Cui Pang, Chaojun Song, Yize Li, Qiaofeng Wang, Xiaosheng Zhu, Jianwei Wu, Yi Tian, Hao Fan, Jinwei Hu, Chen Li, Baolong Wang, Wenchao Liu, Li Fan,

Abstract Acidic pH of lysosomes are closely related to the autophagy, thus well known of the precise lysosomes pH changes will give more information on the autophagy process and status. So far, however, only pH changes in a relative broad range could be indicated, the exactly lysosomes pH detection has ... Read more >>

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Natural killer cells: functional differences in recurrent spontaneous abortion†.

Fan Hao, Xiangyu Zhou, Liping Jin,

Recurrent spontaneous abortion (RSA) is one of the major pregnancy disorders and poses a serious risk to both the mother and the fetus. Although a number of research efforts have been conducted, therapeutic advances for treating RSA have not lived up to their expectations. Hence, other treatments should be explored. ... Read more >>

Biol. Reprod. (Biology of reproduction)
[2020, 102(3):524-531]

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Dietary l-arginine supplementation ameliorates inflammatory response and alters gut microbiota composition in broiler chickens infected with Salmonella enterica serovar Typhimurium.

Beibei Zhang, Guang Li, Muhammad Suhaib Shahid, Liping Gan, Hao Fan, Zengpeng Lv, Shaojia Yan, Yuming Guo,

This study was conducted to investigate the effects of dietary arginine (Arg) supplementation on the inflammatory response and gut microbiota of broiler chickens subjected to Salmonella enterica serovar Typhimurium. One hundred and forty 1-day-old Arbor Acres male birds were randomly assigned to a 2 × 2 factorial arrangement including diet treatment (with ... Read more >>

Poult. Sci. (Poultry science)
[2020, 99(4):1862-1874]

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Precise lysosome pH indicator based on self-decomposable nanoparticles

Cui Pang, Chaojun Song, Yize Li, Qiaofeng Wang, Xiaosheng Zhu, Jianwei Wu, Yi Tian, Hao Fan, Jinwei Hu, Chen Li, Baolong Wang, Wenchao Liu, Li Fan,

Abstract Background Acidic pH of lysosomes are closely related to the autophagy, thus well known of the precise lysosomes pH changes will give more information on the autophagy process and status. So far, however, only pH changes in a relative broad range could be indicated, the exactly lysosomes pH detection ... Read more >>

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Moxibustion for the treatment of primary dysmenorrhea: Protocol for an overview of systematic reviews.

Xue Wang, Jun Xiong, Jun Yang, Ting Yuan, Hao Fan, Yunfeng Jiang, Xiaohong Zhou, Kai Liao, Lingling Xu,

BACKGROUND:Primary dysmenorrhea (PD) is a common gynecological disease, it refers to spasmodic pain in the lower abdomen before, after or during menstruation, accompanied by general discomfort, In severe cases, fainting may occur due to severe pain, reducing the quality of patients' life and imposing a heavy burden on social medical ... Read more >>

Medicine (Baltimore) (Medicine)
[2020, 99(4):e18908]

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G Protein-Coupled Receptors in Asthma Therapy: Pharmacology and Drug Action.

Stacy Gelhaus Wendell, Hao Fan, Cheng Zhang,

Asthma is a heterogeneous inflammatory disease of the airways that is associated with airway hyperresponsiveness and airflow limitation. Although asthma was once simply categorized as atopic or nonatopic, emerging analyses over the last few decades have revealed a variety of asthma endotypes that are attributed to numerous pathophysiological mechanisms. The ... Read more >>

Pharmacol. Rev. (Pharmacological reviews)
[2020, 72(1):1-49]

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Association of TP73-AS1 gene polymorphisms with the risk and survival of gastric cancer in a Chinese Han Population.

Wangwang Chen, Jian Xiao, Liang Shi, Linling Lin, Mingkun Jiang, Yugang Ge, Zengliang Li, Hao Fan, Li Yang, Zekuan Xu,

It was investigated that TP73-AS1(TP73 antisense RNA 1) could function as an oncogene in gastric cancer (GC). The expression and function of long noncoding RNAs (lncRNAs) could be impacted by single nucleotide polymorphisms (SNPs), which are related to cancer susceptibility and prognosis. This study was to reveal the association between ... Read more >>

Artif Cells Nanomed Biotechnol (Artificial cells, nanomedicine, and biotechnology)
[2019, 47(1):3814-3822]

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STRA6 exerts oncogenic role in gastric tumorigenesis by acting as a crucial target of miR-873.

Linling Lin, Jian Xiao, Liang Shi, Wangwang Chen, Yugang Ge, Mingkun Jiang, Zengliang Li, Hao Fan, Li Yang, Zekuan Xu,

BACKGROUND:Increasing evidence shows that stimulated by retinoic acid 6 (STRA6) participates in regulating multiple cancers. However, the biological roles of STRA6 in gastric cancer (GC) remain unknown. This study aimed to investigate the biological function of STRA6 and reveal the underlying mechanism of its dysregulation in GC. METHODS:The expression level ... Read more >>

J. Exp. Clin. Cancer Res. (Journal of experimental & clinical cancer research : CR)
[2019, 38(1):452]

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Anatomical study of the extraocular check ligament system.

Wei Zhuang, Shuo Fang, Hao Fan, Weiye Zhu, Yong Chen, Weiya Tang, Chengling Liu, Xingchen Liu, Zhen Zhang, Xin Xing, Chao Yang,

AIM:To clarify the gross anatomy structure of the check ligament of the palpebra superior in relation to congenital blepharoptosis operation. METHOD:Seven fixed and three fresh cadavers of Chinese adults (between 53 and 76 years old; 5 males and 5 females) were used. Gross dissection was performed on fourteen eyes in ... Read more >>

J Plast Reconstr Aesthet Surg (Journal of plastic, reconstructive & aesthetic surgery : JPRAS)
[2019, 72(12):2017-2026]

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Steroidal constituents from Helleborus thibetanus and their cytotoxicities.

Yu-Ze Li, Hua-Wei Zhang, Hao Fan, Xiao-Fei Liang, Bei Song, Huan Chen, Wen-Li Huang, Zheng-Gang Yue, Xiao-Mei Song, Jian-Li Liu,

Thibetanosides E-H (1-4), four new steroidal constituents including three rare sulfonates (2-4), were isolated from the roots and rhizomes of Helleborus thibetanus, together with nine known steroidal compounds (5-13). Their structures were elucidated by detailed spectroscopic analysis, including 1D and 2D NMR techniques and chemical evidence. In this study, compounds ... Read more >>

Chin J Nat Med (Chinese journal of natural medicines)
[2019, 17(10):778-784]

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In vivo and in vitro protective effect of arginine against intestinal inflammatory response induced by Clostridium perfringens in broiler chickens.

Beibei Zhang, Liping Gan, Muhammad Suhaib Shahid, Zengpeng Lv, Hao Fan, Dan Liu, Yuming Guo,

Background:Necrotic enteritis is a widespread disease in poultry caused by Clostridium perfringens. We previously reported that dietary arginine supplementation protected the intestinal mucosa of broiler chickens with necrotic enteritis, but the related protective mechanisms remain unclear. The in vivo trial was designed as a 2 × 2 factorial arrangement to evaluated the ... Read more >>

J Anim Sci Biotechnol (Journal of Animal Science and Biotechnology)
[2019, 10:73]

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Fine mapping of an up-curling leaf locus (BnUC1) in Brassica napus.

Mao Yang, Chengwei Huang, Mingming Wang, Hao Fan, Shubei Wan, Yangming Wang, Jianbo He, Rongzhan Guan,

BACKGROUND:Leaf shape development research is important because leaf shapes such as moderate curling can help to improve light energy utilization efficiency. Leaf growth and development includes initiation of the leaf primordia and polar differentiation of the proximal-distal, adaxial-abaxial, and centrolateral axes. Changes in leaf adaxial-abaxial polarity formation, auxin synthesis and ... Read more >>

BMC Plant Biol. (BMC plant biology)
[2019, 19(1):324]

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