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Imaging photoelectron transmission through self-assembled monolayers: the work-function of alkanethiols coated gold.

PMID: 17441738 (view PubMed database entry)
DOI: 10.1021/la063471t (read at publisher's website )

Despina Fragouli, Theofanis N Kitsopoulos, Letizia Chiodo, Fabio Della Sala, Roberto Cingolani, Supratim G Ray, Ron Naaman,

In this paper, we present a new approach for studying the electronic properties of self-assembled monolayers and their interaction with a conductive substrate, the low-energy photoelectron imaging spectroscopy (LEPIS). LEPIS relies on imaging of photoelectrons ejected from a conductive substrate and subsequently transmitted through organic monolayers. Using this method, we measure the relative work-function of alkanethiols of different length on gold substrate, and we are able to follow the changes occurring when the surface coverage is varied. We also computed the work-function of model alkanethiols using a plane-wave density functional theory approach, in order to demonstrate the correlation between changes in the work-function with the monolayer organization and density.

Langmuir (Langmuir : the ACS journal of surfaces and colloids)
[2007, 23(11):6156-6162]

Cited: 7 times

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