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Hypervalent iodine-mediated vicinal syn diazidation: application to the total synthesis of (+/-)-dibromophakellstatin.

PMID: 15496054 (view PubMed database entry)
DOI: 10.1021/ol0490532 (read at publisher's website )

Raymond Chung, Eunsun Yu, Christopher D Incarvito, David J Austin,

[reaction: see text] The total synthesis of (+/-)-dibromophakellstatin is described. The molecule is constructed from a key syn-diazide, formed by a hypervalent iodine-mediated diazidation of a dihydrodipyrrolopyrazinone ring structure.

Org. Lett. (Organic letters)
[2004, 6(22):3881-3884]

Cited: 40 times

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